Fenton reaction
Fenton's Reaction is a mechanism for iron to catalyze the formation of oxygen radicals, which are then readily oxidize wort or beer components. More specifically, iron(II)-ions are oxidized to iron(III) by hydrogen peroxide, forming a hydroxyl radical and a hydroxyl ion. The iron(III) eventually reacts with a further molecule of hydrogen peroxide generating two protons and a superoxide radical. These superoxide radicals can also react with copper(II)-ions to copper(I) and oxygen in the Haber-Weiss reaction scheme.[1]
Fe2+ + H2O2 → Fe3+ + OH• + OH– Fe3+ + H2O2 → Fe2+ + O2– + 2H+ Net: 2H2O2 → OH• + OH– + O2– + 2H+
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References[edit]
- ↑ Zufall C, Tyrell Th. The influence of heavy metal ions on beer flavour stability. J Inst Brew. 2008;114(2):134–142.